Solid-state electrochromic device based on two poly(thiophene) derivatives

被引：31

作者：

Ribeiro, AS ^{[1
]}

Machado, DA ^{[1
]}

Filho, PFD ^{[1
]}

De Paoli, MA ^{[1
]}

机构：

[1] UNICAMP, Lab Polimeros Condutores & Reciclagem, Inst Quim, BR-13084971 Campinas, SP, Brazil

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2004年 / 567卷 / 02期

基金：

巴西圣保罗研究基金会;

关键词：

substituted polythiophenes; electrochromic device; spectroelectrochemistry; polymer electrolyte;

D O I：

10.1016/j.jelechem.2003.12.033

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A solid-state electrochromic device was assembled using a polymer electrolyte and optically transparent electrodes modified with thin films of poly{3-[12-(p-methoxyphenoxy)dodecyl]thiophene} and poly(3,4-ethylenedioxythiophene) doped with poly(styrenesulfonate). Poly(epichlorohydrin-co-ethylene oxide) containing LiClO4 was used as the polymer electrolyte. After assembling, the device was studied by spectroelectrochemical techniques. The best performance of this device could be obtained by adjusting the relative thickness of the active polymer films and the potential range of operation of the device. The device shows color variation during ca. 500 charge/discharge cycles and can be constructed under atmospheric conditions. The results obtained suggest a multitude of perspectives in applications in electrochromic displays. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：243 / 248

页数：6

共 33 条

[21] An unusual electrochromic device based on a new low-bandgap conjugated polymer [J].

Meng, H ;

Tucker, D ;

Chaffins, S ;

Chen, YS ;

Helgeson, R ;

Dunn, B ;

Wudl, F .

ADVANCED MATERIALS, 2003, 15 (02) :146-+

[22]

Monk P. M. S., 1995, ELECTROCHROMISM FUND

[23] Electrochromic materials [J].

Mortimer, RJ .

CHEMICAL SOCIETY REVIEWS, 1997, 26 (03) :147-156

[24] In situ conductivity studies of poly(3,4-ethylenedioxythiophene) [J].

Morvant, MC ;

Reynolds, JR .

SYNTHETIC METALS, 1998, 92 (01) :57-61

[25] Poly(ethylene oxide-co-epichlorohydrin)/NaI:: a promising polymer electrolyte for photoelectrochemical cells [J].

Nogueira, AF ;

Spinacé, MAS ;

Gazotti, WA ;

Girotto, EM ;

de Paoli, MA .

SOLID STATE IONICS, 2001, 140 (3-4) :327-335

[26] ELECTROCHROMIC AND HIGHLY STABLE POLY(3,4-ETHYLENEDIOXYTHIOPHENE) SWITCHES BETWEEN OPAQUE BLUE-BLACK AND TRANSPARENT SKY BLUE [J].

PEI, QB ;

ZUCCARELLO, G ;

AHLSKOG, M ;

INGANAS, O .

POLYMER, 1994, 35 (07) :1347-1351

[27] Electrochromic windows: an overview [J].

Rauh, RD .

ELECTROCHIMICA ACTA, 1999, 44 (18) :3165-3176

[28]

Ribeiro A. F., UNPUB

[29] An electrochromic device combining polypyrrole and WO3 .1. Liquid electrolyte [J].

Rocco, AM ;

DePaoli, MA ;

Zanelli, A ;

Mastragostino, M .

ELECTROCHIMICA ACTA, 1996, 41 (18) :2805-2816

[30]

Rosseinsky DR, 2001, ADV MATER, V13, P783, DOI 10.1002/1521-4095(200106)13:11<783::AID-ADMA783>3.0.CO

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