A new topological index for molecular probes used in inverse gas chromatography .2. Application for the evaluation of the solid surface specific interaction potential

被引：65

作者：

Brendle, E ^{[1
]}

Papirer, E ^{[1
]}

机构：

[1] INST CHIM SURFACES & INTERFACES,CNRS,F-68057 MULHOUSE,FRANCE

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 1997年 / 194卷 / 01期

关键词：

inverse gas chromatography; topological index; silica; graphite; specific interaction;

D O I：

10.1006/jcis.1997.5105

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The application of the new morphological index chi(T), which is an extension of Wiener's index for the evaluation of the retention data of apolar and polar solutes used in inverse gas chromatography, is described. Indeed, chi(T) performs satisfactorily, surpassing the other molecular descriptors employed so far. Examples of applications on silica and graphite samples are presented. It appears that the new index allows a unique evaluation of the Lewis acid-base surface characteristics of solid surfaces. (C) 1997 Academic Press.

引用

页码：217 / 224

页数：8

共 20 条

[1]

[Anonymous], 1983, STUD PHYS THEOR CHEM

[2]

Balaban A., 1986, MATCH Commun. Math. Comput. Chem, V21, P115

[3] A new topological index for molecular probes used in inverse gas chromatography for the surface nanorugosity evaluation .1. Method of evaluation [J].

Brendle, E ;

Papirer, E .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1997, 194 (01) :207-216

[4] DETERMINATION OF ACID-BASE PROPERTIES OF SOLID MATERIALS BY INVERSE GAS-CHROMATOGRAPHY AT INFINITE DILUTION - A NOVEL EMPIRICAL-METHOD BASED ON THE DISPERSIVE CONTRIBUTION TO THE HEAT OF VAPORIZATION OF PROBES [J].

CHEHIMI, MM ;

PIGOISLANDUREAU, E .

JOURNAL OF MATERIALS CHEMISTRY, 1994, 4 (05) :741-745

[5]

DONG S, 1989, CHROMATOGRAPHIA, V28, P85

[6] EVALUATION OF SPECIFIC INTERACTIONS OF SOLID-SURFACES BY INVERSE GAS-CHROMATOGRAPHY - A NEW APPROACH BASED ON POLARIZABILITY OF THE PROBES [J].

DONNET, JB ;

PARK, SJ ;

BALARD, H .

CHROMATOGRAPHIA, 1991, 31 (9-10) :434-440

[7]

Gutmann V., 1978, DONOR ACCEPTOR APPRO

[8] MOLECULAR CONNECTIVITY .2. RELATIONSHIP TO WATER SOLUBILITY AND BOILING-POINT [J].

HALL, LH ;

KIER, LB ;

MURRAY, WJ .

JOURNAL OF PHARMACEUTICAL SCIENCES, 1975, 64 (12) :1974-1977

[9] MOLECULAR CONNECTIVITY .1. RELATIONSHIP TO NONSPECIFIC LOCAL ANESTHESIA [J].

KIER, LB ;

HALL, LH ;

MURRAY, WJ ;

RANDIC, M .

JOURNAL OF PHARMACEUTICAL SCIENCES, 1975, 64 (12) :1971-1974

[10] MOLECULAR CONNECTIVITY .7. SPECIFIC TREATMENT OF HETEROATOMS [J].

KIER, LB ;

HALL, LH .

JOURNAL OF PHARMACEUTICAL SCIENCES, 1976, 65 (12) :1806-1809

← 1 2 →