An Efficient and Highly Selective Synthesis of (Z)-Fluoroenol Phosphates from Hydroxy Difluorophosphonates

被引：16

作者：

Beier, Petr ^{[1
]}

Pohl, Radek ^{[1
]}

Alexandrova, Anastasia V. ^{[1
]}

机构：

[1] Acad Sci Czech Republ, Inst Organ Chem & Biochem, CR-16610 Prague 6, Czech Republic

来源：

SYNTHESIS-STUTTGART | 2009年 / 06期

关键词：

phosphonates; phosphates; rearrangements; eliminations; enols; ENOL PHOSPHATES; PERKOW REACTION; KETONES; FLUORINE; PHOSPHITES; ALDEHYDES; CHLORIDES; REAGENTS; MOIETY; ROUTE;

D O I：

10.1055/s-0028-1087803

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Substituted 2-aryl-2-hydroxy-1,1-difluorophosphonates undergo a reaction with potassium tert-butoxide to provide selectively (Z)-2-fluoro-1-arylvinyl phosphates in high yields.

引用

页码：957 / 962

页数：6

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