End-linked poly(dimethylsiloxane) elastomer structure: H-2-NMR transverse dephasing data compared to predictions of statistical and thermodynamic models

被引：32

作者：

McLoughlin, K ^{[1
]}

Szeto, C ^{[1
]}

Duncan, TM ^{[1
]}

Cohen, C ^{[1
]}

机构：

[1] CORNELL UNIV,SCH CHEM ENGN,ITHACA,NY 14853

来源：

MACROMOLECULES | 1996年 / 29卷 / 16期

关键词：

D O I：

10.1021/ma9600320

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

H-2-NMR measurements of deuterated poly(dimethylsiloxane) [PDMS(d)] elastomers with systematically varied elastic and swelling properties are presented. H-2-NMR transverse dephasing data are compared to the predictions of a model describing elastomer deuterium transverse dephasing data as a linear superposition of contributions from elastic and pendant chains. Structural parameters obtained from the model for H-2-NMR transverse dephasing are compared to structural parameters inferred from swelling measurements using statistical and thermodynamic models. As predicted by the model for transverse dephasing data, dephasing time constants for elastic chains are directly proportional to number-average molecular weights of elastic chains obtained from swelling measurements.

引用

页码：5475 / 5483

页数：9