Novel fulleropyrrolidinium-based materials

被引：22

作者：

Carano, M

Ceroni, P

Paolucci, F

Roffia, S

Da Ros, T

Prato, M

Sluch, MI

Pearson, C

Petty, MC

Bryce, MR

机构：

[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

[2] Univ Trieste, Dipartimento Sci Farmaceut, I-34127 Trieste, Italy

[3] Univ Durham, Ctr Mol Elect, Durham DH1 3LE, England

[4] Univ Durham, Sch Engn, Durham DH1 3LE, England

[5] Univ Durham, Dept Chem, Durham DH1 3LE, England

[6] Russian Acad Sci, PN Lebedev Phys Inst, Moscow 1179247, Russia

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2000年 / 10卷 / 02期

关键词：

D O I：

10.1039/a903494c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The cyclic voltammetry of a series of soluble N-methylfulleropyrrolidinium salts shows that these materials are better electron-acceptors than unmodified C-60. The stability of mono-reduced, zwitterionic, and doubly-reduced anionic species, produced either electrochemically or chemically, has been checked by absorption spectroscopy. Langmuir-Blodgett (LB) layers of the C-60 derivatives mixed with tricosanoic acid have been built up on different substrates. The optical properties of the films have been characterized using absorption spectroscopy and their structure was investigated by X-ray diffraction.

引用

页码：269 / 273

页数：5

共 49 条

[1] ORGANIC MOLECULAR SOFT FERROMAGNETISM IN A FULLERENE-C60 [J].

ALLEMAND, PM ;

KHEMANI, KC ;

KOCH, A ;

WUDL, F ;

HOLCZER, K ;

DONOVAN, S ;

GRUNER, G ;

THOMPSON, JD .

SCIENCE, 1991, 253 (5017) :301-303

[2]

[Anonymous], 1993, The Photosynthetic Reaction Center

[3]

Balzani V.S. F., 1991, Supramolecular Photochemistry

[4] THE C-60(2-) FULLERIDE ION [J].

BOYD, PDW ;

BHYRAPPA, P ;

PAUL, P ;

STINCHCOMBE, J ;

BOLSKAR, RD ;

SUN, YP ;

REED, CA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (10) :2907-2914

[5] Enhanced acceptor character in fullerene derivatives. Synthesis and electrochemical properties of fulleropyrrolidinium salts [J].

Da Ros, T ;

Prato, M ;

Carano, M ;

Ceroni, P ;

Paolucci, F ;

Roffia, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (45) :11645-11648

[6] SYNTHESES, STRUCTURES, AND PROPERTIES OF METHANOFULLERENES [J].

DIEDERICH, F ;

ISAACS, L ;

PHILP, D .

CHEMICAL SOCIETY REVIEWS, 1994, 23 (04) :243-255

[7] ELECTROCHEMICAL EVIDENCE FOR THROUGH-SPACE ORBITAL INTERACTIONS IN SPIROMETHANOFULLERENES [J].

EIERMANN, M ;

HADDON, RC ;

KNIGHT, B ;

LI, QC ;

MAGGINI, M ;

MARTIN, N ;

OHNO, T ;

PRATO, M ;

SUZUKI, T ;

WUDL, F .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (15) :1591-1594

[8]

FOX MA, 1989, PHOTOINDUCED ELECT, VA

[9] Intramolecular electron transfer in fullerene/ferrocene based donor-bridge-acceptor dyads [J].

Guldi, DM ;

MAggini, M ;

Scorrano, G ;

Prato, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (05) :974-980

[10] Near IR photoluminescence in mixed films of conjugated polymers and fullerenes [J].

Hasharoni, K ;

KeshavarzK, M ;

Sastre, A ;

Gonzalez, R ;

BellaviaLund, C ;

Greenwald, Y ;

Swager, T ;

Wudl, F ;

Heeger, AJ .

JOURNAL OF CHEMICAL PHYSICS, 1997, 107 (07) :2308-2312

← 1 2 3 4 5 →