Magnetism of lanthanides in molecular materials with transition-metal ions and organic radicals

被引：1527

作者：

Benelli, C ^{[1
]}

Gatteschi, D ^{[1
]}

机构：

[1] Univ Florence, Polo Sci Univ, UdR INSTM, Dept Chem, I-50019 Sesto Fiorentino, Italy

来源：

CHEMICAL REVIEWS | 2002年 / 102卷 / 06期

关键词：

D O I：

10.1021/cr010303r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The understanding of the magnetic interactions involving rare-earth ions in molecular magnets is still far from being satisfactory. The key point is the role of the orbital contribution, which introduces many complications, in particular large magnetic anisotropies. It is necessary to gather a large number of experimental data, and isotropic measurements are not particularly well suited in order to obtain the information which is needed to reconstruct the full map of the magnetic interactions.

引用

页码：2369 / 2387

页数：19

共 124 条

[31] HIGH-TEMPERATURE SPIN DYNAMICS IN ONE-DIMENSIONAL HEISENBERG SYSTEM (CH-3)4NMNCL-3 (TMMC) - SPIN DIFFUSION, INTRACHAIN AND INTERCHAIN CUTOFF EFFECTS
BOUCHER, JP
BAKHEIT, MA
NECHTSCHEIN, M
VILLA, M
BONERA, G
BORSA, F
[J]. PHYSICAL REVIEW B, 1976, 13 (09): : 4098 - 4118
[32] Heterometallic complexes containing d- and f-block elements: Synthesis and structural characterisation of novel Ni-Er and Co-Dy compounds
Brechin, EK
Harris, SG
Parsons, S
Winpenny, REP
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (10): : 1665 - 1666
[33] Synthesis and structural and magnetic characterization of discrete phenolate and imidazolate bridged Gd(III)-M(II) [M = Cu, Ni] dinuclear complexes
Brewer, C
Brewer, G
Scheidt, WR
Shang, MY
Carpenter, EE
[J]. INORGANICA CHIMICA ACTA, 2001, 313 (1-2) : 65 - 70
[34] Remarks on the proper use of the broken symmetry approach to magnetic coupling
Caballol, R
Castell, O
Illas, F
Moreira, PR
Malrieu, JP
[J]. JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (42) : 7860 - 7866
[35] TOWARD MOLECULAR MAGNETS - THE METAL-RADICAL APPROACH
CANESCHI, A
GATTESCHI, D
SESSOLI, R
REY, P
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1989, 22 (11) : 392 - 398
[36] Caneschi A, 2000, ANGEW CHEM INT EDIT, V39, P246, DOI 10.1002/(SICI)1521-3773(20000103)39:1<246::AID-ANIE246>3.3.CO
[37] 2-2
[38] Caneschi A, 2001, ANGEW CHEM INT EDIT, V40, P1760, DOI 10.1002/1521-3773(20010504)40:9<1760::AID-ANIE17600>3.0.CO
[39] 2-U
[40] LONG-RANGE MAGNETIC ORDER IN A GDCU2 CLUSTER WITH A S = 9/2 GROUND-STATE
CARLIN, RL
VAZIRI, M
BENELLI, C
GATTESCHI, D
[J]. SOLID STATE COMMUNICATIONS, 1988, 66 (01) : 79 - 81

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