A novel mixed-ligand molecular bilayer generated by self-assembly of "T-shaped" moieties, displaying an unusual entanglement

被引:55
作者
Fu, ZY [1 ]
Wu, XT [1 ]
Dai, JC [1 ]
Hu, SM [1 ]
Du, WX [1 ]
机构
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China
关键词
D O I
10.1039/b202762c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction of silver nitrate with 4,4'-biphenyldicarboxylate and 1,2-bis(4-pyridyl) ethane under hydrothermal conditions gives an interesting 2D bilayer containing a new kind of "T-shaped" unit. Each of these 2D frames is interlocked with the neighboring layers to form an overall three-dimensional architecture, displaying an unprecedented entanglement.
引用
收藏
页码:978 / 980
页数:3
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