The organometallic chemistry of pentalene

被引:103
作者
Summerscales, Owen T. [1 ]
Cloke, F. Geoffrey N. [1 ]
机构
[1] Univ Sussex, Dept Chem, Sch Life Sci, Brighton BN1 9QJ, E Sussex, England
基金
英国工程与自然科学研究理事会;
关键词
pentalene; sandwich compounds; organometallic; molecular wires; transition metals; f-elements;
D O I
10.1016/j.ccr.2005.11.020
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Carbocyclic, aromatic ligands have always played a central role in the growth of organometallic chemistry. In this review, we present work from our own laboratories and those of others on the development of the coordination chemistry of the eight-membered, bicyclic pentalene ring system, and its application to the synthesis of new types of organometallic compounds throughout the periodic table. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:1122 / 1140
页数:19
相关论文
共 129 条
[41]   GROUND STATES OF CONJUGATED MOLECULES .11. IMPROVED TREATMENT OF HYDROCARBONS [J].
DEWAR, MJS ;
DELLANO, C .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (04) :789-&
[42]  
DIETRICH H, 1997, ANGEW CHEM, V36, P1714
[43]   GROUND-STATE CALCULATIONS OF DI-PI-CYCLOOCTATETRAENE CERIUM [J].
DOLG, M ;
FULDE, P ;
KUCHLE, W ;
NEUMANN, CS ;
STOLL, H .
JOURNAL OF CHEMICAL PHYSICS, 1991, 94 (04) :3011-3017
[44]   FORMALLY TETRAVALENT CERIUM AND THORIUM COMPOUNDS - A CONFIGURATION-INTERACTION STUDY OF CEROCENE CE(C8H8)(2) AND THOROCENE TH(C8H8)(2) USING ENERGY-ADJUSTED QUASI-RELATIVISTIC AB-INITIO PSEUDOPOTENTIALS [J].
DOLG, M ;
FULDE, P ;
STOLL, H ;
PREUSS, H ;
CHANG, A ;
PITZER, RM .
CHEMICAL PHYSICS, 1995, 195 (1-3) :71-82
[45]   Synthesis and structural chemistry of non-cyclopentadienyl organolanthanide complexes [J].
Edelmann, FT ;
Freckmann, DMM ;
Schumann, H .
CHEMICAL REVIEWS, 2002, 102 (06) :1851-1896
[46]   The oxidation state of Ce in the sandwich molecule cerocene [J].
Edelstein, NM ;
Allen, PG ;
Bucher, JJ ;
Shuh, DK ;
Sofield, CD ;
Kaltsoyannis, N ;
Maunder, GH ;
Russo, MR ;
Sella, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (51) :13115-13116
[47]  
EHRTHOLT DJ, 1970, J CHEM SOC CHEM COMM, P1451
[48]   MU-(ETA-5-ETA-5-CYCLOOCTATETRAENE)BIS[ETA-5-CYCLOPENTADIENYL)-VANADIUM] - PREPARATION, STRUCTURE, AND ELECTRON-SPIN-RESONANCE CHARACTERIZATION OF ITS RADICAL-ANION [J].
ELSCHENBROICH, C ;
HECK, J ;
MASSA, W ;
NUN, E ;
SCHMIDT, R .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (09) :2905-2907
[49]  
Elschenbroich C., 1992, ORGANOMETALLICS
[50]  
ELSCHENBROICH CE, 2001, ORGANOMETALLICS