Long-range stereo-relay:: Relative and absolute configuration of 1,n-glycols from circular dichroism of liposomal porphyrin esters

被引：34

作者：

MacMillan, JB ^{[1
]}

Molinski, TF ^{[1
]}

机构：

[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 32期

关键词：

D O I：

10.1021/ja047741a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The relative and absolute configurations of long-chain syn- and anti-1,5-, 1,7- and 1,9-glycols were determined from exciton-coupled circular dichroism (ECCD) of the corresponding bis-5-(4′-carboxyl)-5,10,15,20-tetraphenylporphyrin esters measured in uniform (φ = 26 nm), unilamellar liposomes. Long-range transmission of configuration by ECCD is made possible through partial ordering of glycol ester-lipid molecules by liposomal bilayers. Copyright © 2004 American Chemical Society.

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页码：9944 / 9945

页数：2

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