Bifunctional Dendrimers: From Robust Synthesis and Accelerated One-Pot Postfunctionalization Strategy to Potential Applications

被引：117

作者：

Antoni, Per ^{[1
]}

Hed, Yvonne

Nordberg, Axel ^{[2
,3
]}

Nystrom, Daniel ^{[1
]}

von Holst, Hans ^{[2
,3
]}

Hult, Anders ^{[1
]}

Malkoch, Michael ^{[1
]}

机构：

[1] Royal Inst Technol, Sch Chem & Chem Sci, Div Coating Technol, Stockholm 10044, Sweden

[2] Royal Inst Technol, Sch Technol & Hlth Neuron Engn, Huddinge, Sweden

[3] Karolinska Inst, Dept Clin Neurosci, Stockholm, Sweden

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 12期

关键词：

click chemistry; dendrimers; gels; nanoparticles; synthetic methods; PHOSPHORUS-CONTAINING DENDRIMERS; DENDRITIC MACROMOLECULES; CLICK CHEMISTRY; RAPID SYNTHESIS; TERMINAL ALKYNES; POLYMERS; ARCHITECTURES; MOLECULES; GROWTH; AZIDES;

D O I：

10.1002/anie.200804987

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A fourth wheel: Two sets of bifunctional AB2C dendrimers having internal acetylene/azides and external hydroxy groups were constructed utilizing benign synthetic protocols. An in situ postfunctionalization strategy was successfully carried out to illustrate the chemoselective nature of these dendrimers. The dendrimers were also transformed into dendritic nanoparticles or utilized as dendritic crosslinkers for the fabrication hydrogels. (Figure Presented). © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2126 / 2130

页数：5

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