Equilibrium free-energy differences from nonequilibrium measurements: A master-equation approach

被引：1038

作者：

Jarzynski, C

机构：

[1] Theoretical Astrophysics T-6, Los Alamos National Laboratory, Los Alamos, 87545

来源：

PHYSICAL REVIEW E | 1997年 / 56卷 / 05期

关键词：

D O I：

10.1103/PhysRevE.56.5018

中图分类号：

O35 [流体力学]; O53 [等离子体物理学];

学科分类号：

070204 ; 080103 ; 080704 ;

摘要：

In has recently been shown that the Helmholtz free-energy difference between two equilibrium configurations of a system may be obtained from an ensemble of finite-time (nonequilibrium) measurements of the work performed in switching an external parameter of the system. Here this result is established, as an identity, within the master equation formalism. Examples are discussed and numerical illustrations provided.

引用

页码：5018 / 5035

页数：18

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[11] Kinetic moments method for the canonical ensemble distribution [J].