Influence of fluorination on the properties of carbon fibres

被引:118
作者
Bismarck, A
Tahhan, R
Springer, J
Schulz, A
Klapotke, TM
Zell, H
机构
[1] TU BERLIN,INST TECH CHEM,FACHGEBIET MAKROMOL CHEM,D-10623 BERLIN,GERMANY
[2] UNIV GLASGOW,DEPT CHEM,GLASGOW G12 8QQ,LANARK,SCOTLAND
[3] INST KUNSTSTOFFVERARBEITUNG,D-52056 AACHEN,GERMANY
关键词
carbon fibres; contact angle; ESCA; fluorination; physical properties; XRD;
D O I
10.1016/S0022-1139(97)00029-8
中图分类号
O61 [无机化学];
学科分类号
070301 [无机化学]; 081704 [应用化学];
摘要
Various fluorination methods were applied to modify the surfaces of carbon fibres. Mild fluorination techniques, such as low pressure fluorine at various temperatures and pressures, were compared with strong fluorination agents, such as HF-F-2 mixtures or ClF3. The relationship between the degree of fluorination and the physical and chemical properties of two polyacrylonitrile-based carbon fibres (Torayca, FT 300 6000-99; Sigri, Sigrafil C320.00A) was studied using a combination of contact angle hysteresis, electron spectroscopy for chemical analysis (ESCA), resistivity measurements and X-ray diffraction (XRD). (C) 1997 Elsevier Science S.A.
引用
收藏
页码:127 / 134
页数:8
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