Electrochemical characteristics of the negative electrode in lithium-ion batteries: Effect of structure and surface properties of the carbon material

被引:6
作者
Dubasova, VS [1 ]
Fialkova, AS
Kanevskii, LS
Mikhailova, VA
Nikolenko, AF
Ponomareva, TA
Zaichikov, SG
Baver, AI
Smirnova, TY
机构
[1] Sci & Technol Design Inst Electrocarbon Articles, Elektrougli, Moscow Oblast, Russia
[2] Russian Acad Sci, Frumkin Inst Electrochem, Moscow 119071, Russia
关键词
graphite electrode; carbon; intercalation; lithium-ion battery; graphite;
D O I
10.1023/B:RUEL.0000023926.93541.1a
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Dependence of charge-discharge characteristics of the carbon electrode of a lithium-ion battery on crystallographic and macrostructural parameters of the carbon material and the on conditions of a preliminary treatment of this material are studied. The conclusion is drawn that, in order to obtain a carbon material that would be optimum for the negative electrodes of lithium-ion batteries, it is necessary to couple technological expedients of various types that would take into account the opposite, by the results, action of various factors (in the first place, dispersion of carbon and an increase in the temperature of its thermal treatment) on such electrochemical characteristics of electrodes as the rate of a charge-discharge process and value of its coulombic efficiency. Characteristics of carbon materials, obtained on the basis of domestic raw materials, which ensure efficient operation of such electrodes, are presented.
引用
收藏
页码:369 / 378
页数:10
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