Plasma-initiated controlled/living radical polymerization of methyl methacrylate in the presence of 2-cyanoprop-2-yl 1-dithionaphthalate (CPDN)

被引：39

作者：

Chen, GJ ^{[1
]}

Zhu, XL ^{[1
]}

Zhu, J ^{[1
]}

Cheng, ZP ^{[1
]}

机构：

[1] Suzhou Univ, Sch Chem & Chem Engn, Suzhou 215006, Peoples R China

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2004年 / 25卷 / 07期

关键词：

living polymerization; methyl methacrylate; plasma polymerization; RAFT;

D O I：

10.1002/marc.200300266

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Plasma-initiated controlled/living radical polymerization of methyl methacrylate (MMA) was carried out in the presence of 2-cyanoprop-2-yl 1-dithionaphthalate. Well-defined poly(methyl methacrylate) (PMMA), with a narrow polydispersity, could be synthesized. The polymerization is proposed to occur via a RAFT mechanism. Chain-extension reactions were also successfully carried out to obtain higher molecular weight PMMA and PMMA-block-PSt copolymer.

引用

页码：818 / 824

页数：7

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