Domino Heck-C-H activation reaction of unsymmetrically substituted [3]cumulene

被引：42

作者：

Furuta, Takumi

Asakawa, Tomohiro

Iinuma, Mie

Fujii, Satoshi

Tanaka, Kiyoshi

Kan, Toshiyuki

机构：

[1] Univ Shizuoka, Sch Pharmaceut Sci, Dept Synthet Organ & Med Chem, Shizuoka 4228526, Japan

[2] Univ Shizuoka, Sch Pharmaceut Sci, Dept Phys Biochem, Shizuoka 4228526, Japan

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 34期

关键词：

D O I：

10.1039/b607684j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Heck reaction of an unsymmetrically substituted [3] cumulene has been investigated. Although a carbonyl conjugated alkene is present, the arylpalladium species selectively inserts into the C3-4 double bond, and a subsequent C - H activation reaction with a neighboring phenyl group gives the indene derivatives with a tetrasubstituted olefin moiety.

引用

收藏

页码：3648 / 3650

页数：3

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