Molecular iodine catalyzed selective acetylation of alcohols with vinyl acetate

被引：65

作者：

Bosco, J. W. John ^{[1
]}

Agrahari, Aditya ^{[1
]}

Saikia, Anil K. ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Gauhati 781039, India

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 24期

关键词：

molecular iodine; catalyst; selective; alcohol; acetate; vinyl acetate;

D O I：

10.1016/j.tetlet.2006.03.182

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Molecular iodine is found to catalyze the acetylation of alcohols efficiently with vinyl acetate. The reaction is mild and selective with good to high yields. Molecular iodine displays significant functional group tolerance, being compatible with methoxy, double bonds, spiroketals, ketals and phenolic hydroxyl functions. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：4065 / 4068

页数：4

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