Electrochemical enzymatic deoxygenation of chiral sulfoxides utilizing DMSO reductase

被引：27

作者：

Abo, M ^{[1
]}

Dejima, M ^{[1
]}

Asano, F ^{[1
]}

Okubo, A ^{[1
]}

Yamazaki, S ^{[1
]}

机构：

[1] Univ Tokyo, Dept Appl Biol Chem, Bunkyo Ku, Tokyo 1138657, Japan

来源：

TETRAHEDRON-ASYMMETRY | 2000年 / 11卷 / 03期

关键词：

D O I：

10.1016/S0957-4166(00)00004-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Preparation of enantiomerically enriched sulfoxides by an electrochemical enzymatic system utilizing DMSO reductase was studied. This system consists of a glassy carbon electrode as the working electrode, methyl viologen as the mediator and DMSO reductase from Rhodobacter sphaeroides f. sp. denitrificans as the catalyst. The (R)-enantiomers of chiral sulfoxides in the presence of a variety of functional groups were obtained with high e.e. (>97%) by this system. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：823 / 828

页数：6

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