Sodium-oxygen batteries: a new class of metal-air batteries

被引：155

作者：

Das, Shyamal K. ^{[1
]}

Lau, Sampson ^{[2
]}

Archer, Lynden A. ^{[2
]}

机构：

[1] Tezpur Univ, Dept Phys, Sonitpur 784028, Assam, India

[2] Cornell Univ, Sch Chem & Biomol Engn, Ithaca, NY 14850 USA

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2014年 / 2卷 / 32期

关键词：

NA-ION BATTERIES; ENERGY-STORAGE; ALKYL-CARBONATE; LI-AIR; LITHIUM; PERFORMANCE; ANODE; INTERCALATION; CHALLENGES; TRANSPORT;

D O I：

10.1039/c4ta02176b

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Research on sodium-oxygen batteries has gained unprecedented momentum in recent times. With a high theoretical specific energy of 1600 W h kg(-1) and an equilibrium discharge potential of 2.3 V, a rechargeable sodium-oxygen battery embodies an attractive new metal-air battery platform for applications in transportation. As an earth-abundant element, sodium has the potential to be a low cost replacement for lithium in electrochemical storage technologies while retaining the majority of its qualities. This highlight focuses on the development and current progress in the field of sodium-oxygen batteries. Strategies for improving the reversibility of the electrode reactions and for understanding and overcoming key problems in sodium-oxygen batteries are also discussed.

引用

页码：12623 / 12629

页数：7

共 68 条

[1] Current density dependence of peroxide formation in the Li-O2 battery and its effect on charge [J].

Adams, Brian D. ;

Radtke, Claudio ;

Black, Robert ;

Trudeau, Michel L. ;

Zaghib, Karim ;

Nazar, Linda F. .

ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (06) :1772-1778

[2] Metal-organic frameworks as solid magnesium electrolytes [J].

Aubrey, M. L. ;

Ameloot, R. ;

Wiers, B. M. ;

Long, J. R. .

ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (02) :667-671

[3] Challenges for Na-ion Negative Electrodes [J].

Chevrier, V. L. ;

Ceder, G. .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2011, 158 (09) :A1011-A1014

[4] Silicon-air batteries [J].

Cohn, Gil ;

Starosvetsky, David ;

Hagiwara, Rika ;

Macdonald, Digby D. ;

Ein-Eli, Yair .

ELECTROCHEMISTRY COMMUNICATIONS, 2009, 11 (10) :1916-1918

[5] Facile synthesis and long cycle life of SnSb as negative electrode material for Na-ion batteries [J].

Darwiche, Ali ;

Sougrati, Moulay T. ;

Fraisse, Bernard ;

Stievano, Lorenzo ;

Monconduit, Laure .

ELECTROCHEMISTRY COMMUNICATIONS, 2013, 32 :18-21

[6] Better Cycling Performances of Bulk Sb in Na-Ion Batteries Compared to Li-Ion Systems: An Unexpected Electrochemical Mechanism [J].

Darwiche, Ali ;

Marino, Cyril ;

Sougrati, Moulay T. ;

Fraisse, Bernard ;

Stievano, Lorenzo ;

Monconduit, Laure .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (51) :20805-20811

[7]

Das S. K., EXPT WERE PERF UNPUB

[8] Carbon dioxide assist for non-aqueous sodium-oxygen batteries [J].

Das, Shyamal K. ;

Xu, Shaomao ;

Archer, Lynden A. .

ELECTROCHEMISTRY COMMUNICATIONS, 2013, 27 :59-62

[9] High energy lithium-oxygen batteries - transport barriers and thermodynamics [J].

Das, Shyamal K. ;

Xu, Shaomao ;

Emwas, Abdul-Hamid ;

Lu, Ying Ying ;

Srivastava, Samanvaya ;

Archer, Lynden A. .

ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (10) :8927-8931

[10] ELECTROCHEMICAL INTERCALATION OF SODIUM IN NAXCOO2 BRONZES [J].

DELMAS, C ;

BRACONNIER, JJ ;

FOUASSIER, C ;

HAGENMULLER, P .

SOLID STATE IONICS, 1981, 3-4 (AUG) :165-169

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