A novel Rh-PCy(3)-CO-HCOOH catalytic system for the regioselective conversion of alkenes to aldehydes

被引：10

作者：

ElAli, B ^{[1
]}

Vasapollo, G ^{[1
]}

Alper, H ^{[1
]}

机构：

[1] UNIV OTTAWA,DEPT CHEM,OTTAWA,ON K1N 6N5,CANADA

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1996年 / 112卷 / 02期

基金：

加拿大自然科学与工程研究理事会;

关键词：

rhodium; carbon monoxide; formic acid; regioselectivity; alkene conversion; aldehydes;

D O I：

10.1016/1381-1169(96)00070-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Rhodium carbonyl and tricyclohexylphosphine, in the presence of CO and HCOOH, is an efficient catalytic system for the regioselective conversion of alkenes into branched and linear aldehydes. This process shows excellent functional group tolerance.

引用

页码：195 / 201

页数：7

共 11 条

[1] ZWITTERIONIC RHODIUM COMPLEXES AS CATALYSTS FOR THE HYDROFORMYLATION OF OLEFINS [J].

AMER, I ;

ALPER, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (09) :3674-3676

[2] USE OF FORMIC OR OXALIC-ACID FOR THE REGIOSELECTIVE HYDROCARBOXYLATION OF ALKENES AND ALKYNES CATALYZED BY PD/C AND 1,4-BIS(DIPHENYLPHOSPHINO)BUTANE [J].

ELALI, B ;

VASAPOLLO, G ;

ALPER, H .

JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (17) :4739-4741

[3] FORMIC-ACID PALLADIUM ACETATE-1,4-BIS(DIPHENYLPHOSPHINO)BUTANE - AN EFFECTIVE CATALYTIC-SYSTEM FOR REGIOSELECTIVE HYDROCARBOXYLATION OF SIMPLE AND FUNCTIONALIZED OLEFINS [J].

ELALI, B ;

ALPER, H .

JOURNAL OF MOLECULAR CATALYSIS, 1992, 77 (01) :7-13

[4]

Falbe J., 1980, New Syntheses with Carbon Monoxide

[5] CATALYTIC REACTIONS OF FORMATE .1. PHOTOCATALYTIC HYDROGEN-PRODUCTION FROM FORMATE WITH CHROMIUM HEXACARBONYL [J].

LINN, DE ;

KING, RB ;

KING, AD .

JOURNAL OF MOLECULAR CATALYSIS, 1993, 80 (02) :151-163

[6] CATALYTIC REACTIONS OF FORMATE .2. ALDEHYDE HYDROGENATION USING CHROMIUM HEXACARBONYL [J].

LINN, DE ;

KING, RB ;

KING, AD .

JOURNAL OF MOLECULAR CATALYSIS, 1993, 80 (02) :165-179

[7]

Parshall G.W., 1980, Homogeneous Catalysis: The Applications and Chemistry of Catalysis by Soluble Transition Metal Complexes

[8]

Pruett R.L., 1979, Adv. Organomet. Chem., V17, P1, DOI [10.1016/S0065-3055(08)60329-9, DOI 10.1016/S0065-3055(08)60329-9]

[9] USE OF RHODIUM ON CARBON AND 1,3-BIS(DIPHENYLPHOSPHINO)PROPANE TO CATALYZE THE REGIOSELECTIVE HYDROFORMYLATION OF ALKENES WITH FORMIC-ACID AS THE HYDROGEN SOURCE [J].

SOMASUNDERAM, A ;

ALPER, H .

JOURNAL OF MOLECULAR CATALYSIS, 1994, 92 (01) :35-40

[10] RHODIUM(I) CATALYZED DECOMPOSITION OF FORMIC-ACID [J].

STRAUSS, SH ;

WHITMIRE, KH ;

SHRIVER, DF .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 174 (03) :C59-C62

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