Synthesis, crystal structure and luminescent properties of two cadmium thiocyanate coordination polymers with benzylpyridyl cations

被引：36

作者：

Dang, Dong-Bin ^{[1
]}

Shang, Wei-Li ^{[1
]}

Bai, Yan ^{[1
]}

Sun, Ji-De ^{[1
]}

Gao, Hui ^{[1
]}

机构：

[1] Henan Univ, Sch Chem & Chem Engn, Inst Mol & Crystal Engn, Kaifeng 475004, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2009年 / 362卷 / 07期

基金：

中国国家自然科学基金; 芬兰科学院;

关键词：

Coordination polymers; Cadmium(II) complex; Crystal structure; Luminescence; INORGANIC-ORGANIC HYBRID; MAGNETIC TRANSITION; CHAIN; COMPLEXES; IONS;

D O I：

10.1016/j.ica.2008.10.023

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two luminescent Cd(II) complexes [RBzPy][Cd(SCN)(3)] for R = Cl (1) and Br (2) have been synthesized and structurally characterized. The Cd atoms are all N3S3 hexa-coordinated with six bridging SCN and form infinite [Cd(SCN)(3)](infinity) polymeric chains. The layer arrangement of the anionic chains was obtained using the larger halogenated benzylpyridyl cations. The luminescent properties of 1 and 2 in the solid state were investigated. (C) 2008 Elsevier B. V. All rights reserved.

引用

页码：2391 / 2395

页数：5

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