1D looped chain, 1D tube-like chain, and 3D inorganic-organic hybrid coordination polymers assembled from 1,6-di(triazole-1-yl-methyl)-4-R-phenol and cadmium(II) thiocyanate

被引：31

作者：

Chu, Zhao-Lian ^{[2
]}

Zhu, Hai-Bin ^{[1
]}

Hu, Da-Hua ^{[2
]}

Huang, Wei ^{[2
]}

Gou, Shao-Hua ^{[1
,2
]}

机构：

[1] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Peoples R China

[2] Nanjing Univ, Sch Chem & Chem Engn, Nanjing 210093, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2008年 / 8卷 / 05期

关键词：

D O I：

10.1021/cg700892z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of ligands, 1,6-di(triazole-1-yl-methyl)-4-R-phenol [dttp (R = t-Bu), dtmp (R = Me), dtcp (R = Cl)], with Cd(SCN)(2) leads to the formation of various coordination polymers with different structures. Coordination polymer [Cd(dttP)(2)(SCN)(2)] (1) possesses a one-dimensional (ID) looped chain running along the c-axis, while isostructural polymers [Cd(dtmp)(SCN)(2)center dot CH3OH] (2) and [Cd(dtcp)(SCN)(2)center dot CH3OH] (3) feature a novel ID tilbe-like chain running along the a-axis. Distinct assemblies are observed in 1, 2, and 3 due to the spatial hindrance of different substituted groups bonded to the phenol rings. In contrast, 1,6-di(triazole-1-yl-methyl)-4-chlorophenol (dtcp) with Cd(SCN)(2) under a solvothermal reaction condition yields a remarkable and unique three-dimensional (3D) polymer [Cd(dtcp)(SCN)(2)] (4).

引用

页码：1599 / 1604

页数：6

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