Electron transport through single phenylene-ethynylene molecular junctions at low temperature

被引:60
作者
Khondaker, SI [1 ]
Yao, Z
Cheng, L
Henderson, JC
Yao, YX
Tour, JM
机构
[1] Univ Texas, Dept Phys, Ctr Nano & Mol Sci & Technol, Austin, TX 78712 USA
[2] Univ Texas, Texas Mat Inst, Austin, TX 78712 USA
[3] Rice Univ, Dept Chem, Houston, TX 77005 USA
[4] Rice Univ, Ctr Nanoscale Sci & Technol, Houston, TX 77005 USA
关键词
D O I
10.1063/1.1773915
中图分类号
O59 [应用物理学];
学科分类号
摘要
We present low-temperature electron transport measurements of individual phenylene-ethynylene molecular wires, connected to nanometer-spaced gold electrodes. Low-bias current-voltage (I-V) characteristics measured at 4.2 K are stable and show irregular steps. After application of a large voltage, the low-bias I-V curves switch between different stable configurations, some of which show negative differential resistance (NDR). Similar behavior, including the NDR, has been observed in molecules irrespective of whether they contain a NO2 side group or not. We suggest that different I-V curves measured, including the NDR, could be due either to conformational changes in the molecules or a change in coupling of the molecular junction. (C) 2004 American Institute of Physics.
引用
收藏
页码:645 / 647
页数:3
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