The first discrete mixed-valence hexadecavanadate host shell cluster anions:: hydrothermal synthesis, structure and characterization of [V16O38(Cl)]8-

被引：36

作者：

Chen, YH

Gu, XJ

Peng, J ^{[1
]}

Shi, ZY

Yu, HQ

Wang, E

Hu, NH

机构：

[1] NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Jilin, Peoples R China

[2] Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 05期

基金：

中国国家自然科学基金;

关键词：

hydrothermal synthesis; crystal structure; polyoxovanadate; phen;

D O I：

10.1016/j.inoche.2004.03.021

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学]; 081704 [应用化学];

摘要：

A new compound, [NH4](2)[Zn(phen)(3)](2)[Zn(phen)(2)(H2O)(2)][V16O38(Cl)] (.) 5H(2)O (1), was synthesized in the hydrothermal condition. The "naked" [V16O38(Cl)](8-) is the first observation with host shell structure in polyoxovanadate chemistry. (C) 2004 Published by Elsevier B.V.

引用

页码：705 / 707

页数：3

共 24 条

[1]

BIZHOU L, 2002, CHEM COMMUN, P2126

[2]

BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE [J].