N-H insertion reactions of rhodium carbenoids .2. Preparation of N-substituted amino(phosphoryl)acetates (N-substituted phosphorylglycine esters)

被引：54

作者：

Ferris, L

Haigh, D

Moody, CJ

机构：

[1] LOUGHBOROUGH UNIV TECHNOL,DEPT CHEM,LOUGHBOROUGH LE11 3TU,LEICS,ENGLAND

[2] SMITHKLINE BEECHAM PHARMACEUT,EPSOM KT18 5XQ,SURREY,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1996年 / 24期

关键词：

D O I：

10.1039/p19960002885

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Rhodium(II) acetate-catalysed reaction of ethyl 2-diazo-2-diethoxyphosphorylacetate 2 with carbamates, amides, ureas or anilines gives a range of N-substituted 2-amino-2-diethoxyphosphorylacetates 3-18 by N-H insertion reaction of the intermediate rhodium carbenoid.

引用

页码：2885 / 2888

页数：4

共 51 条

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FERRIS L, 1995, SYNLETT, P921

[12]

GROSS H, 1965, ANGEW CHEM INT EDIT, V4, P975

[13] RHODIUM CARBENOID O-H INSERTION REACTIONS WITH PHENOLS - A FACILE METHOD FOR THE SYNTHESIS OF TRIALKYL 2-ARYLOXYPHOSPHONOACETATES AND THEIR USE IN THE PREPARATION OF 2-ARYLOXY-3-PHENYLPROPANOATES [J].