Low frequency Raman active vibrations in fullerenes. 2. Quadrupolar modes

被引：19

作者：

Eisler, HJ ^{[1
]}

Hennrich, FH ^{[1
]}

Gilb, S ^{[1
]}

Kappes, MM ^{[1
]}

机构：

[1] Univ Karlsruhe, Inst Phys Chem, D-76128 Karlsruhe, Germany

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 2000年 / 104卷 / 08期

关键词：

D O I：

10.1021/jp9932618

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The lowest frequency Raman active (molecular) vibrations of known fullerenes are quadrupolar in nature (QP modes). They can be simply rationalized in terms of the 5-fold degenerate D-g oscillation of an isotropic spherical shell. Symmetry distortion away fi-om spherical leads to lifting of the degeneracy and correspondingly up to five vibrational features may be resolved in the QP-mode regions of the Raman spectra of high fullerenes. The energy splitting is a measure of fullerene cage topology.

引用

页码：1769 / 1773

页数：5

共 16 条

[1]

ACHIBA Y, 1995, MATER RES SOC SYMP P, V359, P3

[2] Ring-opening vibrations of spherosiloxanes [J].

Bornhauser, P ;

Calzaferri, G .

JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (06) :2035-2044

[3]

BUERGI HB, 1992, ANGEW CHEM INT EDIT, V31, P640

[4] C-60 VIBRATES AS A HOLLOW SPHERE [J].

CEULEMANS, A ;

FOWLER, PW ;

VOS, I .

JOURNAL OF CHEMICAL PHYSICS, 1994, 100 (08) :5491-5500

[5] On the vibrational modes of C-60 [J].

Clougherty, DP ;

Gorman, JP .

CHEMICAL PHYSICS LETTERS, 1996, 251 (5-6) :353-356

[6]

DRESSELHAUS MS, 1988, SPRINGER SERIES MAT

[7] FAR-INFRARED AND RAMAN VIBRATIONAL TRANSITIONS OF A SOLID SPHERE - SELECTION-RULES [J].

DUVAL, E .

PHYSICAL REVIEW B, 1992, 46 (09) :5795-5797

[8] Low frequency Raman active vibrations in fullerenes. 1. Monopolar modes [J].

Eisler, HJ ;

Gilb, S ;

Hennrich, FH ;

Kappes, MM .

JOURNAL OF PHYSICAL CHEMISTRY A, 2000, 104 (08) :1762-1768

[9]

HENNRICH FH, 1996, ANGEW CHEM, V108, P1839

[10] NMR CHARACTERIZATION OF ISOMERS OF C-78, C-82 AND C-84 FULLERENES [J].

KIKUCHI, K ;

NAKAHARA, N ;

WAKABAYASHI, T ;

SUZUKI, S ;

SHIROMARU, H ;

MIYAKE, Y ;

SAITO, K ;

IKEMOTO, I ;

KAINOSHO, M ;

ACHIBA, Y .

NATURE, 1992, 357 (6374) :142-145

← 1 2 →