Application of random-search algorithm for regression analysis of catalytic hydrogenations

被引:35
作者
Belohlav, Z
Zamostny, P
Kluson, P
Volf, J
机构
[1] Institute of Chemical Technology, Department of Organic Technology, Prague 166 28
关键词
experiment evaluation; non-linear regression; confidence regions; likelihood ratio;
D O I
10.1002/cjce.5450750411
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A short review of the works concerning parameter estimation in kinetic experiments was performed. An adaptive random search algorithm was applied to evaluate the parameters and parameter confidence intervals of Langmuir-Hinshelwood models. The kinetic parameters were determined using the Box - Draper criterion. The parameter confidence regions were found by using the likelihood ratio. Three heterogeneously catalyzed hydrogenations were studied.
引用
收藏
页码:735 / 742
页数:8
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