Spectral analysis for systems of atoms and molecules coupled to the quantized radiation field

被引:160
作者
Bach, V
Fröhlich, J
Sigal, IM
机构
[1] Tech Univ Berlin, FB Math MA 7 2, D-10623 Berlin, Germany
[2] ETH Honggerberg, Inst Theoret Phys, CH-8093 Zurich, Switzerland
[3] Univ Toronto, Dept Math, Toronto, ON M5S 3G3, Canada
关键词
D O I
10.1007/s002200050726
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We consider systems of static nuclei and electrons - atoms and molecules - coupled to the quantized radiation field. The interactions between electrons and the soft mode-s of the quantized electromagnetic field are described by minimal coupling, p --> p - eA(x), where A(x) is the electromagnetic vector potential with an ultraviolet cutoff. If the interactions between the electrons and the quantized radiation field are turned off, the atom or molecule is assumed to have at least one bound state. We prove that, for sufficiently small values of the fine structure constant alpha, the interacting system has a ground state corresponding to the bottom of its energy spectrum. For an atom, we prove that:its excited states above the ground state turn into metastable States whose lifetimes we estimate. Furthermore the energy spectrum is absolutely continuous, except, perhaps. in a small interval above the ground state energy and around the threshold energies of the atom or molecule.
引用
收藏
页码:249 / 290
页数:42
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