Recent progress in asymmetric two-center catalysis

被引：270

作者：

Shibasaki, M ^{[1
]}

Kanai, M ^{[1
]}

Funabashi, K ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Pharmaceut Sci, Bunkyo Ku, Tokyo 1130033, Japan

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 18期

关键词：

D O I：

10.1039/b203495f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Recent progress using two types of enantioselective two-center catalysts, Lewis acid-Bronsted base and Lewis acid-Lewis base bifunctional complexes, is described. The first part of this review discusses improvements in the syn-selective direct catalytic enantioselective aldol reaction and 1,4-addition reaction of a 2-hydroxyacetophenone derivative using a Zn-linked-BINOL complex. In the second part, we describe the development of catalysts displaying Lewis acidity and Lewis basicity in a catalytic enantioselective cyanosilylation of aldehydes and the logical extension to a tetrasubstituted carbon synthesis through a Reissert-type reaction and a cyanosilylation of ketones.

引用

页码：1989 / 1999

页数：11

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