1,2-diphenylethylenediamine linked chiral Ti(IV) complex - a new entry to the highly enantioselective silylcyanation of aliphatic and aromatic aldehydes

被引：43

作者：

Chang, CW ^{[1
]}

Yang, CT ^{[1
]}

Hwang, CD ^{[1
]}

Uang, BJ ^{[1
]}

机构：

[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 300, Taiwan

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 01期

关键词：

D O I：

10.1039/b107867d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Highly enantioselective silylcyanation of aliphatic and aromatic aldehydes was achieved by using a 1,2-diphenylethylenediamine linked chiral Ti(IV) complex as the catalyst.

引用

页码：54 / 55

页数：2

共 44 条

[1] Asymmetric trimethylsilylcyanation of aldehydes catalyzed by chiral (salen)Ti(IV) complexes. [J].

Belokon, Y ;

Ikonnikov, N ;

Moscalenko, M ;

North, M ;

Orlova, S ;

Tararov, V ;

Yashkina, L .

TETRAHEDRON-ASYMMETRY, 1996, 7 (03) :851-855

[2] Asymmetric trimethylsilylcyanation of benzaldehyde catalyzed by (salen)Ti(IV) complexes derived from (R)- and/or (S)-4-hydroxy-5-formyl[2.2]paracyclophane and diamines [J].

Belokon, Y ;

Moscalenko, M ;

Ikonnikov, N ;

Yashkina, L ;

Antonov, D ;

Vorontsov, E ;

Rozenberg, V .

TETRAHEDRON-ASYMMETRY, 1997, 8 (19) :3245-3250

[3]

BELOKON Y, 1997, J CHEM SOC P1, V1, P1293

[4] Vanadium-catalyzed asymmetric cyanohydrin synthesis [J].

Belokon, YN ;

North, M ;

Parsons, T .

ORGANIC LETTERS, 2000, 2 (11) :1617-1619

[5] The asymmetric addition of trimethylsilyl cyanide to aldehydes catalyzed by chiral (salen)titanium complexes [J].

Belokon, YN ;

Caveda-Cepas, S ;

Green, B ;

Ikonnikov, NS ;

Krustalev, VN ;

Larichev, VS ;

Moscalenko, MA ;

North, M ;

Orizu, C ;

Tararov, VI ;

Tasinazzo, M ;

Timofeeva, GI ;

Yashkina, LV .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (16) :3968-3973

[6] Optimized catalysts for the asymmetric addition of trimethylsilyl cyanide to aldehydes and ketones [J].

Belokon, YN ;

Green, B ;

Ikonnikov, NS ;

North, M ;

Parsons, T ;

Tararov, VI .

TETRAHEDRON, 2001, 57 (04) :771-779

[7] ENANTIOSELECTIVE TRIMETHYLSILYLCYANATION OF ALDEHYDES [J].

BOLM, C ;

MULLER, P .

TETRAHEDRON LETTERS, 1995, 36 (10) :1625-1628

[8] Sulfoximine-titanium reagents in enantioselective trimethylsilylcyanations of aldehydes [J].

Bolm, C ;

Muller, P ;

Harms, K .

ACTA CHEMICA SCANDINAVICA, 1996, 50 (04) :305-315

[9] BIO-ORGANIC SYNTHESIS OF OPTICALLY-ACTIVE CYANOHYDRINS AND ACYLOINS [J].

BRUSSEE, J ;

ROOS, EC ;

VANDERGEN, A .

TETRAHEDRON LETTERS, 1988, 29 (35) :4485-4488

[10]

EFFENBERGER F, 1994, ANGEW CHEM INT EDIT, V33, P1555, DOI 10.1002/anie.199415551

← 1 2 3 4 5 →