1,2-diphenylethylenediamine linked chiral Ti(IV) complex - a new entry to the highly enantioselective silylcyanation of aliphatic and aromatic aldehydes

被引：43

作者：

Chang, CW ^{[1
]}

Yang, CT ^{[1
]}

Hwang, CD ^{[1
]}

Uang, BJ ^{[1
]}

机构：

[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 300, Taiwan

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 01期

关键词：

D O I：

10.1039/b107867d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Highly enantioselective silylcyanation of aliphatic and aromatic aldehydes was achieved by using a 1,2-diphenylethylenediamine linked chiral Ti(IV) complex as the catalyst.

引用

页码：54 / 55

页数：2

共 44 条

[21] ENANTIOSELECTIVE TRIMETHYLSILYLCYANATION OF SOME ALDEHYDES PROMOTED BY MODIFIED SHARPLESS CATALYST [J].

HAYASHI, M ;

MATSUDA, T ;

OGUNI, N .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (19) :1364-1365

[22] ASYMMETRIC CARBON-CARBON BOND-FORMING REACTIONS CATALYZED BY CHIRAL SCHIFF BASE-TITANIUM ALKOXIDE COMPLEXES [J].

HAYASHI, M ;

OGUNI, N .

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 1994, 52 (06) :488-497

[23] ASYMMETRIC CARBON-CARBON BOND-FORMING REACTIONS CATALYZED BY CHIRAL SCHIFF BASE-TITANIUM ALKOXIDE COMPLEXES [J].

HAYASHI, M ;

INOUE, T ;

MIYAMOTO, Y ;

OGUNI, N .

TETRAHEDRON, 1994, 50 (15) :4385-4398

[24] ENANTIOSELECTIVE TRIMETHYLSILYLCYANATION OF SOME ALDEHYDES BY CHIRAL TITANIUM SCHIFFS BASE COMPLEXES [J].

HAYASHI, M ;

MIYAMOTO, Y ;

INOUE, T ;

OGUNI, N .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (24) :1752-1753

[25] Enantioselective addition of trimethylsilyl cyanide to aldehydes induced by a new chiral Ti(IV) complex [J].

Hwang, CD ;

Hwang, DR ;

Uang, BJ .

JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (20) :6762-6763

[26] Trimethylsilylcyanation of aromatic aldehydes catalyzed by Pybox-AlCl3 complex [J].

Iovel, I ;

Popelis, Y ;

Fleisher, M ;

Lukevics, E .

TETRAHEDRON-ASYMMETRY, 1997, 8 (08) :1279-1285

[27] Salen-Ti(OR)(4) complex catalysed trimethylsilylcyanation of aldehydes [J].

Jiang, YZ ;

Gong, LZ ;

Feng, XM ;

Hu, WH ;

Pan, WD ;

Li, Z ;

Mi, AQ .

TETRAHEDRON, 1997, 53 (42) :14327-14338

[28] ASYMMETRIC-SYNTHESIS .22. ASYMMETRIC CATALYTIC TRIMETHYLSILYLCYANATION OF BENZALDEHYDE BY NOVEL TI(IV)-CHIRAL SCHIFF-BASE COMPLEXES [J].

JIANG, YZ ;

ZHOU, XG ;

HU, WH ;

WU, LJ ;

MI, AQ .

TETRAHEDRON-ASYMMETRY, 1995, 6 (02) :405-408

[29] ENANTIOSELECTIVE ADDITION-REACTION OF TRIMETHYLSILYL CYANIDE WITH ALDEHYDES USING A CHIRAL TIN(II) LEWIS ACID [J].

KOBAYASHI, S ;

TSUCHIYA, Y ;

MUKAIYAMA, T .

CHEMISTRY LETTERS, 1991, (04) :541-544

[30] A SIMPLE TOTAL SYNTHESIS OF NATURALLY-OCCURRING HYDROXY-AMINO ACIDS BY ENZYMATIC KINETIC RESOLUTION [J].

LU, Y ;

MIET, C ;

KUNESCH, N ;

POISSON, JE .

TETRAHEDRON-ASYMMETRY, 1993, 4 (05) :893-902

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