ASYMMETRIC-SYNTHESIS .22. ASYMMETRIC CATALYTIC TRIMETHYLSILYLCYANATION OF BENZALDEHYDE BY NOVEL TI(IV)-CHIRAL SCHIFF-BASE COMPLEXES

被引：63

作者：

JIANG, YZ

ZHOU, XG

HU, WH

WU, LJ

MI, AQ

机构：

[1] Chengdu Institute of Organic Chemistry, Academia, Sinica

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 02期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1016/0957-4166(95)00025-K

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Benzaldehyde has been trimethylsilylcyanated with a catalyst prepared in situ from titanium tetraisopropoxide and a novel chiral Schiff base. Both (R) and (S) cyanohydrins are obtained in moderate e.e. values.

引用

页码：405 / 408

页数：4

共 13 条

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