The dinuclear manganese complex Mn2O(OAc)2(TPTN) as a catalyst for epoxidations with hydrogen peroxide

被引:70
作者
Brinksma, J
Hage, R
Kerschner, J
Feringa, BL
机构
[1] Univ Groningen, Stratingh Inst, Organ Chem Lab, NL-9747 AG Groningen, Netherlands
[2] Unilever Res Labs Vlaardingen, NL-3130 AC Vlaardingen, Netherlands
[3] Unilever Res US, Edgewater, NJ 07020 USA
关键词
D O I
10.1039/a910232i
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In acetone and at ambient temperature, the dinuclear manganese complex of TPTN is able to catalyse the oxidation of several alkenes to the corresponding epoxides with high turnovers numbers (up to 900) using H2O2 as oxidant.
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页码:537 / 538
页数:2
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