Perfluoroalkanes

被引：71

作者：

Sandford, G ^{[1
]}

机构：

[1] Univ Durham, Dept Chem, Durham DH1 3LE, England

来源：

TETRAHEDRON | 2003年 / 59卷 / 04期

关键词：

perfluoroalkanes; saturated perfluorocarbons; carbon-fluorine bond activation; perfluorination;

D O I：

10.1016/S0040-4020(02)01568-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The continuing advances in perfluorination technology now allows the synthesis of a greater variety of perfluoroalkanes, for which a chemistry, involving carbon-fluorine bond activation by a variety of electron donors, is emerging. Of course, the preparation of multi functional perfluoro-alkenes and aromatic systems in two steps from commodity hydrocarbon feedstocks via perfluoroalkanes is also a very useful and effective example of carbon-hydrogen bond activation, a topic that has received considerable worldwide interest.147,148 Perfluoroalkanes have, additionally, over the years, been adapted for use for many commercial and synthetic laboratory applications and these continue to grow.

引用

页码：437 / 454

页数：18

共 154 条

[91] COLLISIONALLY INDUCED DISSOCIATION MASS-SPECTROMETRIC STUDIES OF PERFLUORINATED 1H-HEPTANE, TERT-BUTANOL, 2-BUTYLTETRAHYDROFURAN AND ISOPROPYL BROMOBUTYL ETHER [J].