Casteel-Amis equation: Its extension from univariate to multivariate and its use as a two-parameter function

被引:20
作者
Ding, MS [1 ]
机构
[1] USA, Res Lab, Adelphi, MD 20783 USA
关键词
D O I
10.1021/je049839a
中图分类号
O414.1 [热力学];
学科分类号
摘要
The report describes the background of the empirical Casteel-Amis equation and its application to fitting experimental data of conductivity as a function of salt content in electrolytes. It further summarizes the attempts since its publication to extend the equation from a univariate to a multivariate function to include additional variables such as temperature and solvent composition, focusing on that to extend it to a bivariate function of salt content and solvent composition with examples from the solutions of LiPF6, LiBF4, LiBOB, Et4NPF6, and Et4NBF4 in propylene carbonate (PC) + diethyl carbonate and in PC + ethylene carbonate and LiClO4 in PC + acetonitrile. In addition, I discuss, along with experimental data and functional analysis, the validity of using this equation as a two-parameter function in relation to the range of salt content.
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页码:1469 / 1474
页数:6
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