The structural chemistry of copper(II) hinokitiol and its adducts

被引：16

作者：

Barret, MC

Mahon, MF

Molloy, KC

Wright, P

Creeth, JE

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

[2] Unilever Res, Port Sunlight Labs, Wirral L63 3SW, Merseyside, England

来源：

POLYHEDRON | 2002年 / 21卷 / 17期

关键词：

copper; hinokitiol; X-ray; adduct;

D O I：

10.1016/S0277-5387(02)01064-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structure of copper(II) hinokitiol has been determined. Two modifications are possible, one containing only isolated, four-coordinate, square-planar complexes, while a second modification contains both monomers, along with eclipsed and staggered dimers generated through intermolecular O-->Cu interactions. Five-coordinate copper is also present in the adduct Cu(hino)(2). pyridine, whose structure has also been determined for comparison. (C) 2002 Elsevier Science Ltd. All rights reserved.

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页码：1761 / 1766

页数：6

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