Cleavage of a carbon-carbon triple bond via gold-catalyzed cascade cyclization/oxidative cleavage reactions of (Z)-enynols with molecular oxygen

被引：172

作者：

Liu, Yuanhong ^{[1
]}

Song, Feijie ^{[1
]}

Guo, Shenghai ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 35期

关键词：

D O I：

10.1021/ja062610q

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly efficient carbon-carbon triple bond cleavage reaction of (Z)-enynols was developed, which offered a new route to highly substituted butenolides. The methodology is realized by a tandem reaction using a single gold(I) catalyst, which could catalyze different reactions of cyclization/oxidative cleavage in the same vessel. Copyright © 2006 American Chemical Society.

引用

页码：11332 / 11333

页数：2

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