Plasticized nanocomposite polymer electrolytes based on poly(oxyethylene) and cellulose whiskers

被引:69
作者
Samir, MASA
Mateos, AM
Alloin, F
Sanchez, JY
Dufresne, A
机构
[1] LEPMI INPG, F-38402 St Martin Dheres, France
[2] Univ Grenoble 1, Ctr Rech Macromol Vegetales, CERMAV, CNRS, F-38041 Grenoble 9, France
[3] Ecole Francaise Papeterie & Ind Graph, EFPG INPG, F-38402 St Martin Dheres, France
关键词
nanocomposite; polymer electrolyte; dynamic mechanical analysis; plasticizer;
D O I
10.1016/j.electacta.2004.05.021
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Nanocomposite polymer electrolytes based on a plasticized high molecular weight poly(oxyethylene) (POE) reinforced with high aspect ratio cellulose nanoparticles were reported. The influence of tetra(ethylene) glycol dimethyl ether (TEGDME) as plasticizer is investigated. The study mainly focuses on the dynamic mechanical behavior and ionic conductivity performances. The miscibility of the blend POE/ TEGDME was investigated using both thermal and mechanical investigations. Viable polymer electrolytes can be obtained from this combination. conciliating acceptable ionic conductivities and outstanding mechanical performances on a large temperature range. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:4667 / 4677
页数:11
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