Transition metal catalysis in organic synthesis: reflections, chirality and new vistas

被引：50

作者：

Kocovsky, P ^{[1
]}

Malkov, AV

Vyskocil, S

Lloyd-Jones, GC

机构：

[1] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England

[2] Univ Glasgow, Dept Chem, Glasgow G12 8QQ, Lanark, Scotland

[3] Charles Univ Prague, Dept Organ Chem, Prague 12840 2, Czech Republic

[4] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

来源：

PURE AND APPLIED CHEMISTRY | 1999年 / 71卷 / 08期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1351/pac199971081425

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The power of transition metal catalysis as a tool in organic synthesis is exemplified by the recent progress in the following areas: (i) diastereocontrol of Pd(0)-, Mo(0)-, and Ni(0)-catalyzed allylic substitution; (ii) Pd(0)-catalyzed asymmetric allylic substitution; (iii) Hartwig-Buchwald amination; and (iv) Suzuki coupling. Development of novel, bidentate binaphthyl ligands (MAP) and their unique mode of P,C-sigma-coordination is also described.

引用

页码：1425 / 1433

页数：9

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