Fine chemical synthesis with homogeneous palladium catalysts: examples, status and trends

被引:367
作者
Zapf, A [1 ]
Beller, M [1 ]
机构
[1] Univ Rostock, Inst Organ Katalyseforsch, D-18055 Rostock, Germany
关键词
carborylation; cross coupling reactions; fine chemicals; homogeneous catalysis; palladium;
D O I
10.1023/A:1013889401432
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
During the last decade several palladium-catalyzed reactions have been developed and optimized to a stage that enables application on an industrial scale. The importance of these reactions as novel key steps for fine chemical synthesis is shown. Examples include palladium-catalyzed Heck, Suzuki and Sonogashira coupling reactions, telomerization of 1,3-butadiene with nucleophiles, and carbonylation of aromatic and benzylic halides.
引用
收藏
页码:101 / 109
页数:9
相关论文
共 133 条
  • [1] ARYLATION AND ALKYLATION OF OLEFINS BY ARYLAMINES OR HYDRAZINES VIA CARBON-NITROGEN BOND-CLEAVAGE IN THE PRESENCE OF PALLADIUM(II) SALTS
    AKIYAMA, F
    MIYAZAKI, H
    KANEDA, K
    TERANISHI, S
    FUJIWARA, Y
    ABE, M
    TANIGUCHI, H
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (12) : 2359 - 2361
  • [2] Molecularly defined palladium(0) monophosphine complexes as catalysts for efficient cross-coupling of aryl chlorides and phenylboronic acid
    Andreu, MG
    Zapf, A
    Beller, M
    [J]. CHEMICAL COMMUNICATIONS, 2000, (24) : 2475 - 2476
  • [3] [Anonymous], 2013, ANGEW CHEM, V125, P4315, DOI DOI 10.1002/1521-3757(20001117)112:22
  • [4] [Anonymous], 1998, TRANSITION METALS OR
  • [5] [Anonymous], ANGEW CHEM
  • [6] [Anonymous], TRANSITION METALS OR
  • [7] [Anonymous], [No title captured], Patent No. 385210
  • [8] [Anonymous], [No title captured]
  • [9] ASHCROFT CP, 2001, Patent No. 1088817
  • [10] Bader RR, 1996, CHIMIA, V50, P99