Fine chemical synthesis with homogeneous palladium catalysts: examples, status and trends

被引:367
作者
Zapf, A [1 ]
Beller, M [1 ]
机构
[1] Univ Rostock, Inst Organ Katalyseforsch, D-18055 Rostock, Germany
关键词
carborylation; cross coupling reactions; fine chemicals; homogeneous catalysis; palladium;
D O I
10.1023/A:1013889401432
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
During the last decade several palladium-catalyzed reactions have been developed and optimized to a stage that enables application on an industrial scale. The importance of these reactions as novel key steps for fine chemical synthesis is shown. Examples include palladium-catalyzed Heck, Suzuki and Sonogashira coupling reactions, telomerization of 1,3-butadiene with nucleophiles, and carbonylation of aromatic and benzylic halides.
引用
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页码:101 / 109
页数:9
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