Flow injection chemiluminescence determination of sulfide by oxidation with N-bromosuccinimide and N-chlorosuccinimide

被引：83

作者：

Safavi, A ^{[1
]}

Karimi, MA ^{[1
]}

机构：

[1] Shiraz Univ, Fac Sci, Dept Chem, Shiraz 71454, Iran

来源：

TALANTA | 2002年 / 57卷 / 03期

关键词：

chemiluminescence (CL); sulfide; N-bromosuccinimide (NBS); N-chlorosuccinimide (NCS);

D O I：

10.1016/S0039-9140(02)00048-6

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A rapid and sensitive flow injection chemiluminescence method is described for the determination of sulfide based on the chemiluminescence generated during its reaction with either N-bromosuccinimide (NBS) or N-chlorosuccinimide (NCS) in alkaline medium. The results of investigation of the sensitized and non-sensitized chemiluminescence reactions are presented. The emission intensity is greatly enhanced for both NBS- and NCS-sulfide chemiluminescence systems if dichlorofluorescein (for NBS-sulfide) and fluorescein (for NCS-sulfide) are presented in the reaction solutions. The methods were applied satisfactorily to the determination of sulfide in spring water samples. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：491 / 500

页数：10

共 49 条

[21] FLOW-INJECTION PROCEDURE FOR THE DETERMINATION OF TERTIARY-AMINES IN WATER AND SEA-WATER USING CHEMI-LUMINESCENCE DETECTION [J].