Asymmetric benzoin reaction catalyzed by benzoylformate decarboxylase

被引：72

作者：

Demir, AS

Dünnwald, T

Iding, H

Pohl, M

Müller, M

机构：

[1] Forschungszentrum Julich, Inst Biotechnol 1, D-52425 Julich, Germany

[2] Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey

[3] Univ Dusseldorf, Forschungszentrum Julich, Inst Enzymtechnol, D-52426 Julich, Germany

来源：

TETRAHEDRON-ASYMMETRY | 1999年 / 10卷 / 24期

关键词：

D O I：

10.1016/S0957-4166(99)00516-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Aromatic aldehydes are converted into benzoins by benzoylformate decarboxylase catalyzed C-C bond formation. The reaction affords (R)-benzoins with high enantiomeric excess and in good chemical yields. A broad range of aromatic aldehydes can be used as substrates in aqueous buffer or buffer/DMSO-solutions. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：4769 / 4774

页数：6

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