Cleaner Continuous Photo-Oxidation Using Singlet Oxygen in Supercritical Carbon Dioxide

被引：75

作者：

Bourne, Richard A. ^{[1
]}

Han, Xue ^{[1
]}

Poliakoff, Martyn ^{[1
]}

George, Michael W. ^{[1
]}

机构：

[1] Univ Nottingham, Sch Med, Nottingham NG7 2RD, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 29期

基金：

英国工程与自然科学研究理事会;

关键词：

oxidation; photochemistry; singlet oxygen; supercritical fluids; sustainable chemistry; PHOTOSENSITIZED PRODUCTION; GREEN PHOTOCHEMISTRY; CHEMICAL-SYNTHESIS; CHEMISTRY; SOLVENT; HYDROGENATION; CONVERSION; OXIDATION; XENON; STATE;

D O I：

10.1002/anie.200901731

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High pressure under the spotlight: A new milliliter-scale reactor is developed for using supercritical CO 2 to perform continuous photo-oxidation reactions. Changing from a traditional microliter-scale batch reaction to 8 hours of reaction using the new reactor gives a 3000-fold scale-up of the oxidation of α-terpinene (see picture). © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5322 / 5325

页数：4

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