Transient effects can change identifiability criteria for complex excited-state processes

被引：7

作者：

Molski, A

Boens, N

Ameloot, M

机构：

[1] KATHOLIEKE UNIV LEUVEN,DEPT CHEM,B-3001 HEVERLEE,BELGIUM

[2] LIMBURGS UNIV CTR,B-3590 DIEPENBEEK,BELGIUM

来源：

CHEMICAL PHYSICS LETTERS | 1997年 / 266卷 / 1-2期

关键词：

D O I：

10.1016/S0009-2614(96)01523-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The identifiability of two-state excited-state processes is studied when transient effects are present. When the emission bands of the excited species are well separated, the deactivation rate constants of the two excited species to their respective ground states, k(01) and k(02), can be determined from two decay traces of the individual excited species at one concentration. Thus, two decay traces are sufficient for the recovery of k(01) and k(02) for inter- and intra-molecular two-state excited-state processes. When transient effects are absent more kinetic information is needed for the recovery of k(01) and k(02). (C) 1997 Published by Elsevier Science B.V.

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页码：139 / 144

页数：6

相关论文

共 14 条

[1] NON A PRIORI ANALYSIS OF FLUORESCENCE DECAY SURFACES OF EXCITED-STATE PROCESSES .1. THEORY [J].

AMELOOT, M ;

BOENS, N ;

ANDRIESSEN, R ;

VANDENBERGH, V ;

DESCHRYVER, FC .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (05) :2041-2047

[2] NON A PRIORI ANALYSIS OF FLUORESCENCE DECAY SURFACES OF EXCITED-STATE PROCESSES .2. INTERMOLECULAR EXCIMER FORMATION OF PYRENE [J].

ANDRIESSEN, R ;

BOENS, N ;

AMELOOT, M ;

DESCHRYVER, FC .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (05) :2047-2058

[3]

[Anonymous], 1987, Statistical Thermodynamics of Nonequilibrium Processes

[4] LIFETIME RECOVERY FOR SPECIES PARTICIPATING IN COMPLEX KINETICS - APPLICATION TO THE REVERSIBLE EXCIMER [J].

BERBERANSANTOS, MN ;

FARINHA, JP ;

MARTINHO, JMG ;

DUHAMEL, J ;

WINNIK, MA .

CHEMICAL PHYSICS LETTERS, 1992, 189 (4-5) :328-332

[5] EXCIMERS [J].

BIRKS, JB .

REPORTS ON PROGRESS IN PHYSICS, 1975, 38 (08) :903-974

[6]

BOENS N, 1993, BIOPHYS CHEM, V48, P301, DOI 10.1016/0301-4622(93)85017-C

[7] KINETICS AND IDENTIFIABILITY OF INTRAMOLECULAR 2-STATE EXCITED-STATE PROCESSES - GLOBAL COMPARTMENTAL ANALYSIS OF THE FLUORESCENCE DECAY SURFACE [J].

BOENS, N ;

ANDRIESSEN, R ;

AMELOOT, M ;

VANDOMMELEN, L ;

DESCHRYVER, FC .

JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (15) :6331-6342

[8] DIFFUSION EFFECTS ON RAPID BIMOLECULAR CHEMICAL-REACTIONS [J].

KEIZER, J .

CHEMICAL REVIEWS, 1987, 87 (01) :167-180

[9] TEST OF A MODEL FOR REVERSIBLE EXCIMER KINETICS - PYRENE IN CYCLOHEXANOL [J].

MARTINHO, JMG ;

FARINHA, JP ;

BERBERANSANTOS, MN ;

DUHAMEL, J ;

WINNIK, MA .

JOURNAL OF CHEMICAL PHYSICS, 1992, 96 (11) :8143-8149

[10] KINETICS OF NONSTATIONARY, DIFFUSION-INFLUENCED REVERSIBLE-REACTIONS IN SOLUTION [J].

MOLSKI, A ;

KEIZER, J .

JOURNAL OF CHEMICAL PHYSICS, 1992, 96 (02) :1391-1398