Formation of single layer h-BN on Pd(111)

被引:160
作者
Morscher, M. [1 ]
Corso, M. [1 ]
Greber, T. [1 ]
Osterwalder, J. [1 ]
机构
[1] Univ Zurich, Inst Phys, CH-8057 Zurich, Switzerland
关键词
hexagonal boron nitride (h-BN); palladium; Moire pattern; scanning tunneling microscopy (STM); low energy electron diffraction (LEED);
D O I
10.1016/j.susc.2006.06.016
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The structure of hexagonal boron nitride (h-BN) on Pd(111) was studied with low energy electron diffraction (LEED), photoelectron spectroscopy and scanning tunnelling microscopy (STM). h-BN forms flat monolayers on the Pd(111) surface in contrast to Rh(111) where a complex self-assembled double layer structure, the nanomesh [M. Corso, W. Auwarter, M. Muntwiler, A. Tamai, T. Greber, J. Osterwalder, Science 303 (2004) 217], appears. The LEED patterns reveal a dominating 10 x 10 h-BN superstructure, with a second, distinct structure rotated by 30 degrees and further azimuthally randomly oriented h-BN overlayers. This is consistent with STM images which show several different Moire patterns associated with different rotation angles of the overlayer. Additionally the use of thin Pd(111) films instead of single crystal substrates was studied. No significant differences in the h-BN film quality were found. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:3280 / 3284
页数:5
相关论文
共 16 条
[1]   XPD and STM investigation of hexagonal boron nitride on Ni(111) [J].
Auwärter, W ;
Kreutz, TJ ;
Greber, T ;
Osterwalder, J .
SURFACE SCIENCE, 1999, 429 (1-3) :229-236
[2]   The Bronsted-Evans-Polanyi relation and the volcano curve in heterogeneous catalysis [J].
Bligaard, T ;
Norskov, JK ;
Dahl, S ;
Matthiesen, J ;
Christensen, CH ;
Sehested, J .
JOURNAL OF CATALYSIS, 2004, 224 (01) :206-217
[3]   h-BN on Pd(110):: a tunable system for self-assembled nanostructures? [J].
Corso, M ;
Greber, T ;
Osterwalder, J .
SURFACE SCIENCE, 2005, 577 (2-3) :L78-L84
[4]   Boron nitride nanomesh [J].
Corso, M ;
Auwärter, W ;
Muntwiler, M ;
Tamai, A ;
Greber, T ;
Osterwalder, J .
SCIENCE, 2004, 303 (5655) :217-220
[5]   Nucleation of boron nitride thin films on Ni(100) [J].
Desrosiers, RM ;
Greve, DW ;
Gellman, AJ .
SURFACE SCIENCE, 1997, 382 (1-3) :35-48
[6]   Density functional theory investigation of the geometric and spintronic structure of h-BN/Ni(111) in view of photoemission and STM experiments -: art. no. 085404 [J].
Grad, GB ;
Blaha, P ;
Schwarz, K ;
Auwärter, W ;
Greber, T .
PHYSICAL REVIEW B, 2003, 68 (08)
[7]   A photoelectron spectrometer for k-space mapping above the Fermi level [J].
Greber, T ;
Raetzo, O ;
Kreutz, TJ ;
Schwaller, P ;
Deichmann, W ;
Wetli, E ;
Osterwalder, J .
REVIEW OF SCIENTIFIC INSTRUMENTS, 1997, 68 (12) :4549-4554
[8]   Single layer hexagonal boron nitride films on Ni(110) [J].
Greber, Thomas ;
Brandenberger, Louis ;
Corso, Martina ;
Tamai, Anna ;
Osterwalder, Jurg .
E-JOURNAL OF SURFACE SCIENCE AND NANOTECHNOLOGY, 2006, 4 :410-413
[9]   STM INVESTIGATION OF SINGLE LAYER GRAPHITE STRUCTURES PRODUCED ON PT(111) BY HYDROCARBON DECOMPOSITION [J].
LAND, TA ;
MICHELY, T ;
BEHM, RJ ;
HEMMINGER, JC ;
COMSA, G .
SURFACE SCIENCE, 1992, 264 (03) :261-270
[10]   Symmetry versus commensurability:: Epitaxial growth of hexagonal boron nitride on Pt(111) from B-trichloroborazine (ClBNH)3 [J].
Müller, F ;
Stöwe, K ;
Sachdev, H .
CHEMISTRY OF MATERIALS, 2005, 17 (13) :3464-3467