Facile fabrication of nanocellular block copolymer thin films using supercritical carbon dioxide

被引：65

作者：

Li, L

Yokoyama, H

Nemoto, T

Sugiyama, K

机构：

[1] Natl Inst Adv Ind Sci & Technol, Nanotechnol Res Inst, Tsukuba, Ibaraki 3058565, Japan

[2] Tokyo Inst Technol, Grad Sch Sci & Engn, Dept Organ & Polymer Mat, Meguro Ku, Tokyo 1528552, Japan

来源：

ADVANCED MATERIALS | 2004年 / 16卷 / 14期

关键词：

D O I：

10.1002/adma.200400264

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel, facile, and reproducible method of fabricating nanocells in thin films (see Figure) has been developed using a fluorinated block copolymer with a supercritical carbon dioxide (scCO(2)) soluble block as a template. The nanocells have an average spacing of 34 nm and a number density of 9 X 10(10) cm(-2). The size of nanocellular structures is readily tunable by changing the saturation pressure of scCO(2).

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页码：1226 / +

页数：5

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