Syntheses and structures of two- and three-dimensional coordination networks generated from silver complexes and hmt (hmt = hexamethylenetetramine)

被引：32

作者：

Bu, WM ^{[1
]}

Ye, L ^{[1
]}

Fan, YG ^{[1
]}

机构：

[1] Jilin Univ, Key Lab Supramol Struct & Spect, Changchun 130023, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2000年 / 3卷 / 04期

基金：

中国国家自然科学基金;

关键词：

crystal structures; coordination networks; Ag(I) complexes; silver-hmt networks; molecular building;

D O I：

10.1016/S1387-7003(00)00045-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ag(CO2PhCO2)Ag reacts with hexamethylenetetramine (hmt) in acetonitrile solution in the ratio 1:2 to yield the network [Ag-2(mu(3)-hmt)(2)(mu-O2CPhCO2)]. 7H(2)O, in which AgCO2PhCO2Ag units intercalate between the two-dimensional honeycomb-like layers to give a three-dimensional open network, while Ag(MePhSO,) reacts with hmt in the ratio 2:1 to produce the coordination network Ag-2(mu(4)-hmt) (MePhSO3)(2), consisting of two-dimensional grids with square cavities. The X-ray diffraction studies show that these two metal complexes can be used as molecular building blocks in the synthesis of silver-hut networks. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：194 / 197

页数：4

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