Hydrolysis of esters in subcritical and supercritical water

被引:213
作者
Krammer, P [1 ]
Vogel, H [1 ]
机构
[1] Tech Univ Darmstadt, Fac Chem, Dept Chem Technol, D-64287 Darmstadt, Germany
关键词
esters; hydrolysis; kinetics; mechanism; supercritical; water;
D O I
10.1016/S0896-8446(99)00032-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The task of this work was to gain a better understanding of the hydrolysis of esters in sub- and supercritical water (SCW). Therefore, the kinetics of the hydrolysis of ethyl acetate as a model reaction was studied in the pressure and temperature range of 23-30 MPa and 250-400 degrees C, respectively. The corresponding reaction mechanisms in sub- and supercritical water were discussed. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:189 / 206
页数:18
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