Hydrolysis of esters in subcritical and supercritical water

被引：213

作者：

Krammer, P ^{[1
]}

Vogel, H ^{[1
]}

机构：

[1] Tech Univ Darmstadt, Fac Chem, Dept Chem Technol, D-64287 Darmstadt, Germany

来源：

JOURNAL OF SUPERCRITICAL FLUIDS | 2000年 / 16卷 / 03期

关键词：

esters; hydrolysis; kinetics; mechanism; supercritical; water;

D O I：

10.1016/S0896-8446(99)00032-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The task of this work was to gain a better understanding of the hydrolysis of esters in sub- and supercritical water (SCW). Therefore, the kinetics of the hydrolysis of ethyl acetate as a model reaction was studied in the pressure and temperature range of 23-30 MPa and 250-400 degrees C, respectively. The corresponding reaction mechanisms in sub- and supercritical water were discussed. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：189 / 206

页数：18

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