Recent advances in automobile exhaust catalysts

被引:345
作者
Matsumoto, SI [1 ]
机构
[1] Toyota Motor Co Ltd, Mat Engn Div 1, Aichi 4718572, Japan
关键词
oxygen storage capacity; three-way catalyst; NO(x) storage-reduction catalyst; sulfur poisoning; steam reforming; hexagonal cell;
D O I
10.1016/j.cattod.2004.04.048
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Catalysts, which were recently developed by Toyota for the control of automobile exhaust, are reviewed. (1) For use in low emission vehicles, a CeO(2)-ZrO(2) solid solution (CZ) with both high oxygen storage capacity and high heat resistance was developed as a support for a high performance three-way catalyst (TWC). (2) A novel three-way catalyst named the NO(x) storage-reduction catalyst (NSR) was developed for automotive lean-burn engines. The NSR catalyst can store NO(x) in an oxidizing atmosphere and then reduce stored NO(x) at stoichiometric or reducing conditions. Also, it has high tolerance to sulfur poisoning which is the most stringent problem for the NSR catalyst. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:183 / 190
页数:8
相关论文
共 36 条
[31]   SELECTIVE CATALYTIC REDUCTION OF NOX WITH N-FREE REDUCTANTS [J].
SHELEF, M .
CHEMICAL REVIEWS, 1995, 95 (01) :209-225
[32]   Improvement of oxygen storage capacity of CeO2-ZrO2 solid solution by heat treatment in reducing atmosphere [J].
Suda, A ;
Ukyo, Y ;
Sobukawa, H ;
Sugiura, M .
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 2002, 110 (02) :126-130
[33]   Store and release of oxygen of ceria-zirconia solid solution synthesized by solid phase reaction at near room temperature [J].
Suda, A ;
Sobukawa, H ;
Suzuki, T ;
Kandori, T ;
Ukyo, Y ;
Sugiura, M .
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 2001, 109 (03) :177-180
[34]   UPTAKE OF NO GAS BY YBA2CU3OY [J].
TABATA, K ;
FUKUDA, H ;
KOHIKI, S ;
MIZUNO, N ;
MISONO, M .
CHEMISTRY LETTERS, 1988, (05) :799-802
[35]  
Tanabe T., 2001, STUD SURF SCI CATAL, V138, P135, DOI [10.1016/S0167-2991(01)80223-9, DOI 10.1016/S0167-2991(01)80223-9]
[36]   SELECTIVE REDUCTION OF NITRIC-OXIDE OVER PLATINUM CATALYSTS IN THE PRESENCE OF SULFUR-DIOXIDE AND EXCESS OXYGEN [J].
ZHANG, G ;
YAMAGUCHI, T ;
KAWAKAMI, H ;
SUZUKI, T .
APPLIED CATALYSIS B-ENVIRONMENTAL, 1992, 1 (03) :L15-L20